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CHEM 267 – PHOTOCHEMISTRY, Spring 2023
(last updated Monday, June 5, 2023 @ 12:27 pm PT)
COURSE INFORMATION
Syllabus
INSTRUCTOR
Professor Shane Ardo
Office Hours: Mondays @ 8 – 9 am, 4:30 – 5:30 pm (use Zoom link)
MEETING DATES AND TIMES
Lecture: Tuesdays & Thursdays @ 9:30 - 10:50 am (SSTR 101)
Discussion: Fridays @ 11 – 11:50 am (HICF 100N)
NOTABLE DUE DATES AND TIMES (10% of lowest score will be dropped, leaving 90% for course grade determination)
Examinations (50% of course grade)
- W5/10 @ noon – Th5/18 @ noon: Asynchronous Non-Proctored Midterm Exam (24 hours to complete; 20% of course grade)
- S6/10 @ noon – Su6/18 @ noon: Asynchronous Non-Proctored Final Exam (24 hours to complete; 30% of course grade)
Synchronous e-Presentation (20% of course grade)
- T6/6, Th6/8, F6/9 (use Zoom link)
e-Presentation Guidelines [POSTED on 5/16]
Assigned Schedule and Topics [POSTED on 5/27]
Synchronous Participation (30% of course grade): journal article reading and critical assessments
COURSE SCHEDULE AND ASSIGNMENTS
WEEK 1 – Z. R. Grabowski & W. Rubaszewska, Journal of the Chemical Society, Faraday Transactions 1, 1977, 73, 11 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 1)
- T4/4: Lecture Notes 01 – Introduction + Physical Chemistry 1 (3 slides per page, Video-Recorded Lecture 01 (see Canvas course website)) [POSTED on 4/4; UPDATED on 4/7]
- Syllabus
- pKa(H3O+(aq)) = 0: E. C. Meister, M. Willeke, W. Angst, A. Togni, and P. Walde, Helvetica Chimica Acta, 2014, 97, 1
- pKa(H3O+(aq)) = 0: T. P. Silverstein and S. T. Heller, Journal of Chemical Education, 2017, 94, 690
- Square Schemes: R. Tyburski, T. Liu, S. D. Glover and L. Hammarström, Journal of the American Chemical Society, 2021, 143, 560
- Th4/6: Lecture Notes 02 – Physical Chemistry 2 (3 slides per page, Video-Recorded Lecture 02 (see Canvas course website)) [POSTED on 4/6; UPDATED on 4/7]
WEEK 2 – S. W. Boettcher, S. Z. Oener, M. C. Lonergan, Y. Surendranath, S. Ardo, C. Brozek & P. A. Kempler, ACS Energy Letters, 2021, 6, 261 (read this article to brush up on your understanding of electrochemical potential)
WEEK 3 – J. C. Bui, I. Digdaya, C. Xiang, A. T. Bell & A. Z. Weber, ACS Applied Materials & Interfaces, 2020, 12, 52509 (be prepared to discuss Tables 1–3 and associated text and equations in this article during discussion session, and answer/discuss problems for Quiz 2)
WEEK 4 – W. J. Albery, Annual Review of Physical Chemistry, 1980, 31, 227 (be prepared to discuss Pages 227 – 244, including Figure 14, during discussion session, and answer/discuss problems for Quiz 3) [POSTED on 4/27]
- T4/25: Lecture Notes 05 – Thermal (Dark) Reactions 2 (3 slides per page, Video-Recorded Lecture 05 (see Canvas course website)) [POSTED on 4/27]
- Marcus Inverted Region Behavior: L. T. Calcaterra, J. R. Miller, and G. L. Closs, Journal of the American Chemical Society, 1984, 106, 3047
- Marcus Inverted Region Behavior: G. L. Closs and J. R. Miller, Science, 1988, 240, 440
- Marcus Theories: R. A. Marcus, Faraday Discussions of the Chemical Society, 1982, 74, 7
- QM Wavefunction Overlap in Marcus–Hush Theory: M. D. Newton, International Journal of Quantum Chemistry, 1980, 18, 363
- QM Wavefunction Overlap in Marcus–Hush Theory: N Sutin, Accounts of Chemical Research, 1982, 15, 275
- QM Tunneling in Marcus–Hush Theory: H. B. Gray and J. R. Winkler, Proceedings of the National Academy of Sciences of the U.S., 2005, 102, 3534
- QM Strong Coupling in Marcus–Hush Theory: C. Creutz and H. Taube, Journal of the American Chemical Society, 1969, 91, 3988
- QM Strong Coupling in Marcus–Hush Theory: B. S. Brunschwig, C. Creutz, and N. Sutin, Chemical Society Reviews, 2002, 31, 168
- Th4/27: Lecture Notes 06 – Thermal (Dark) Reactions 3 (3 slides per page, Video-Recorded Lecture 06 (see Canvas course website)) [POSTED on 4/27]
- Quantifying Self-Exchange Electron-Transfer Rates: D. L. Jameson and R. Anand, Journal of Chemical Education, 2000, 77, 88
- Quantifying Self-Exchange Electron-Transfer Rates: S. Ardo and G. J. Meyer, Journal of the American Chemical Society, 2011, 133, 15384
- Marcus Cross Relations: R. A. Marcus and N. Sutin, Biochimica et Biophysica Acta, 1985, 811, 265
- Interfacial Charge Transfer: J. O'M. Bockris and Z. Nagy, Journal of Chemical Education, 1973, 50, 839
- Marcus–Gerischer Electron-Transfer Theory at Metal Electrodes: C. E. D. Chidsey, Science, 1991, 251, 919
- Marcus–Gerischer Electron-Transfer Theory at Metal Electrodes: H. D. Sikes, J. F. Smalley, S. P. Dudek, A. R. Cook, M. D. Newton, C. E. D. Chidsey, and S. W. Feldberg, Science, 2001, 291, 1519
WEEK 5 – C. E. D. Chidsey, Science, 1991, 251, 919 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 4) [POSTED on 5/4]
WEEK 6 – N. Sutin, Accounts of Chemical Research, 1982, 15, 275 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 5) [POSTED on 5/9]
- T5/9: Lecture Notes 08 – Photophysical Processes 2 (3 slides per page, Video-Recorded Lecture 08 (see Canvas course website)) [POSTED on 5/9]
- Marcus–Gerischer Electron-Transfer Theory at Semiconductor Electrodes: T. W. Hamann, F. Gstrein, B. S. Brunschwig, and N. S. Lewis, Journal of the American Chemical Society, 2005, 127, 7815
- Marcus–Gerischer Electron-Transfer Theory at Semiconductor Electrodes: T. W. Hamann, F. Gstrein, B. S. Brunschwig, and N. S. Lewis, Journal of the American Chemical Society, 2005, 127, 13949
WEEK 7 – C. Mongin, S. Garakyaraghi, N. Razgoniaeva, M. Zamkov & F. N. Castellano, Science, 2016, 351, 369 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 6) [POSTED on 5/18]
WEEK 8 – D. Rehm & A. Weller, Israel Journal of Chemistry, 1970, 8, 259 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 7) [POSTED on 5/24]
WEEK 9 – J. R. Bolton, Science, 1978, 202, 705 (be prepared to discuss this article during discussion session, and answer/discuss problems for Quiz 8) [POSTED on 6/2]
- T5/30: Lecture Notes 11 – Photophysical Processes 5 (3 slides per page, Video-Recorded Lecture 11 (see Canvas course website)) [POSTED on 6/2]
- Th6/1: Lecture Notes 12 – Photochemical Processes 1 (3 slides per page, Video-Recorded Lecture 12 (see Canvas course website)) [POSTED on 6/2; UPDATED on 6/5]
- Photon Recycling: P. Asbeck, Journal of Applied Physics, 1977, 48, 820
- Photon Recycling: V. Badescu & P. T. Landsberg, Semiconductor Science and Technology, 1993, 8, 1267
- Solar Energy Conversion Losses: A. Polman & H. A. Atwater, Nature Materials, 2012, 11, 174
- Photoelectrochemical Kinetics: A. Kumar, P. G. Santangelo & N. S. Lewis, Journal of Physical Chemistry, 1992, 96, 834
- Photoelectrochemical Load Line Analysis: R. E. Rocheleau & E. L. Miller, International Journal of Hydrogen Energy, 1997, 22, 771
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